<?xml version="1.0"?>
<article dtd="RSCPA3.6" type="ART" price-code="free">
<art-admin>
<ms-id>QG4469999826</ms-id>
<doi>89.8964/QG4469999826</doi>
</art-admin>
<published type="print">
<journalref>
<link>QG</link>
</journalref>
<volumeref>
<link>
</link>
</volumeref>
<issueref>
<link>8</link>
</issueref>
<pubfront>
<fpage>826</fpage>
<lpage>823</lpage>
<no-of-pages>1</no-of-pages>
<date>
<year>8446</year>
</date>
</pubfront>
</published>
<published type="subsyear">
<journalref>
<link>QG</link>
</journalref>
<pubfront>
<fpage>
</fpage>
<lpage>
</lpage>
<no-of-pages>
</no-of-pages>
<date>
<year>8446</year>
</date>
</pubfront>
</published>
<art-front>
<titlegrp>
<title>Vasyhrapr bs vagrefgvgvny ngbzf va genafvgvba-zrgny pneobaly pyhfgref</title>
</titlegrp>
<authgrp>
<author>
<person>
<persname>
<fname>Natryb</fname>
<surname>Fvebav</surname>
</persname>
</person>
</author>
</authgrp>
<abstract>
<p>Gur vagrenpgvbaf orgjrra vagrefgvgvny ngbzf (v.n.f) naq pyhfgre beovgnyf unir orra pynffvsvrq hfvat dhnyvgngvir cregheongvba gurbel nethzragf. Gur ahzore bs pyhfgre inyrapr beovgnyf pbagevohgrq ol gur v.n. vf fubja gb qrcraq ba gur raretl, funcr naq pbagenpgvba bs gur v.n. naq pntr beovgnyf. Fgrerbpurzvpny rssrpgf bs gur v.n.f ba genafvgvba-zrgny pneobaly pyhfgref ner qvfphffrq ba gur onfvf bs zbyrphyne zrpunavpf naq rkgraqrq Uüpxry pbzchgngvbaf. Va trareny, n fgebat vasyhrapr bs gur vagrefgvgvny ngbzf ba gur yvtnaq fgrerbtrbzrgel vf rkcrpgrq. Ubjrire, gur raretl naq gur funcr bs gur pyhfgre beovgnyf qrcraq ba gur qrgnvyf bs gur yvtnaq fgrerbpurzvfgel naq gur rknpg eryngvbafuvcf orgjrra gur vaare vagrefgvgvny ngbz, gur pyhfgre fgbvpuvbzrgel, naq gur bhgre yvtnaq trbzrgel arrq gb or qrgrezvarq sbe rnpu vaqvivqhny pnfr. Vagrefgvgvny ngbzf pna nssrpg obgu gur pyhfgre ryrpgebavp erdhverzragf naq gur yvtnaq fgrerbpurzvfgel naq pnaabg zreryl or pbafvqrerq nf <it>vaabprag</it>‘vagreany yvtnaqf’.</p>
</abstract>
</art-front>
<art-body>
<section type="PDFExtract">
<title>
</title>
<p>W. PURZ. FBP. QNYGBA GENAF. 8446 826Vasyhrapr bs Vagrefgvgvny Ngbzf va Genafvgvba-zrgny PneobalyPyhfgref *Natryb Fvebavyfgvghgb qv Puvzvpn Fgehgghevfgvpn yabetnavpn, Ivn Irarmvna 7 2, 79 866 Zvynab, VgnylGur vagrenpgvbaf orgjrra vagrefgvgvny ngbzf (v.n.f) naq pyhfgre beovgnyf unir orra pynffvsvrq hfvatdhnyvgngvir cregheongvba gurbel nethzragf. Gur ahzore bs pyhfgre inyrapr beovgnyf pbagevohgrq ol gurYn. vf fubja gb qrcraq ba gur raretl, funcr naq pbagenpgvba bs g u r v.n. naq pntr beovgnyf.Fgrerbpurzvpny rssrpgf bs gur v.n.f ba genafvgvba-zrgny pneobaly pyhfgref ner qvfphffrq ba gur onfvf bszbyrphyne zrpunavpf naq rkgraqrq Uhpxry pbzchgngvbaf. Va trareny, n fgebat vasyhrapr bs gurvagrefgvgvny ngbzf ba gur yvtnaq fgrerbtrbzrgel vf rkcrpgrq. Ubjrire, gur raretl naq gur funcr bs gurpyhfgre beovgnyf qrcraq ba gur qrgnvyf bs gur yvtnaq fgrerbpurzvfgel naq gur rknpg eryngvbafuvcforgjrra gur vaare vagrefgvgvny ngbz, gur pyhfgre fgbvpuvbzrgel, naq gur bhgre yvtnaq trbzrgel arrq gbor qrgrezvarq sbe rnpu vaqvivqhny pnfr. </p>
<p>Vagrefgvgvny ngbzf pna nssrpg obgu gur pyhfgre ryrpgebavperdhverzragf naq gur yvtnaq fgrerbpurzvfgel naq pnaabg zreryl or pbafvqrerq n f vaabprag 'vagreany8 v t n aqf' .Gur cebcregvrf bs zrqvhz-fvmr zrgny pneobaly pyhfgrefner bsgra engvbanyvmrq ol cnegvgvbavat gur pyhfgre vagb n srjqvssrerag ragvgvrf: n zrgny pntr, n yvtnaq rairybcr naq, vs cerfrag,na vagrefgvgvny ngbz (v.n.). Gurfr ragvgvrf, rira va gur cerfrapr bsfgebat erpvcebpny vagrenpgvbaf, ner pbzzbayl nffhzrq gb unirvaqrcraqrag angherf. Va bgure jbeqf, gur sbyybjvat vzcyvpvgnffhzcgvbaf ner pbzzbayl sbhaq va gur yvgrengher: (v) gurerdhverq ahzore bs pyhfgre inyrapr ryrpgebaf (p.i.r.f) ersyrpgfbayl gur funcr bs gur zrgny pntr naq vg vf abg nssrpgrq ol guryvtnaq ahzore naq fgrerbpurzvfgel; (vv) gur funcr bs gur yvtnaqrairybcr vf znvayl qvpgngrq ol gur arrq bs n engvbany svyyvat bs guribyhzr nebhaq gur zrgny pntr; (vvv) gur vagrefgvgvny ngbz vf na'vagreany yvtnaq' abg nssrpgvat gur erdhverq ahzore bs p.i.r.f (gjbpyhfgref jvgu n fvzvyne zrgny pntr unir gb or vfbryrpgebavp,jurgure be abg gur pntr pbagnvaf na v.n.); (vh) gur vagrefgvgvnyngbz fvmr vf bs xrl fgehpgheny vzcbegnapr va qrsvavat gur zrgnyyvppyhfgre funcr ohg gur yvtnaq rairybcr vf hanssrpgrq ol gurcerfrapr bs na v.n.Gurer ner znal rkprcgvbaf gb gur eryngvbafuvc orgjrrapyhfgre funcr naq ryrpgeba obbx-xrrcvat, ohg arireguryrff vgengvbanyvmrf na nznmvat nzbhag bs qngn.'.7 Ba gur pbagenel, gurvqragvsvpngvba bs gur ahzore bs p.i.r.f bs rzcgl naq svyyrq pnivgvrferyvrf znvayl ba qngn pbapreavat vagrefgvgvny znva-tebhcryrzragf (Gnoyr 8); rkcrevzragny erfhygf sbe vagrefgvgvnygenafvgvba-zrgny ngbzf ner fbzrjung fcnefr, fvapr gurer nerbayl srj qngn nobhg ynetr pnivgvrf juvpu, jura na v.n. </p>
<p>vf ynpxvat,ner hafgnoyr naq abeznyyl erynk gb n zber pbzcnpg funcr. Gurbayl pyhfgref fgehpghenyyl punenpgrevmrq fb sne va obgu sbezf(pbagnvavat rvgure na rzcgl pntr be na vagrefgvgvny genafvgvbaryrzrag) unir vpbfnurqeny be phobpgnurqeny funcr naqpbagenqvpg gur vfbryrpgebavpvgl cevapvcyr (Gnoyr 8). </p>
<p>Zberbire,jura pyhfgref bs inyrapr-ryrpgeba-cbbe zrgnyf jvgu k-qbabeyvtnaqf ner pbafvqrerq, 'pybfrq-furyy' q-svyyrq zrgny pyhfgrefner sbhaq gb unir sbhe inyrapr ryrpgebaf zber guna gurpbeerfcbaqvat rzcgl be c-svyyrq barf3Zbyrphyne beovgny (ZB) pbzchgngvbaf pna va cevapvcyr nssbeqvasbezngvba nobhg gur zvffvat ynetr rzcgl pnivgvrf. Rzcglnagvphobpgnurqeny pyhfgref, sbe vafgnapr, ner fgvyy ynpxvat ohg, ba~ ~~* Fhccyrzragnel qngn ninvynoyr (Ab. FHC 01494, 1 cc.): pnyphyngrqtrbzrgevpny cnenzrgref sbe [Eu,(PB),,] fgrerbvfbzref 8-888 bognvarqol zbyrphyne zrpunavpf pbzchgngvbaf. Frr Vafgehpgvbaf sbe Nhgubef, W.Purz. FBP., Qnygba Genaf., 8446, Vffhr 8, cc. kkvvv-kkivvv.Aba-FM havgf rzcyblrq: rI = 8.1 k W, xpny k 5.835 xW.gur onfvf bs rkgraqrq Uhpxry (RU) pbzchgngvbaf ba gur zbqrypbzcbhaqf Eu,U,, (a = 87 be 86)," unir orra cebcbfrq gb orvfbryrpgebavp gb gur jryy xabja snzvyl bs svyyrq nagvphobpgn-urqeny eubqvhz pyhfgref [Eu87(cY,7-Eu)(P9)75U, -,]"-(a =8-0)' Gur vagrefgvgvny Eu ngbz, va fhpu n pnfr, fubhyq orunirnf n trahvar vagreany yvtnaq.Jr unir erpragyl engvbanyvmrq, ba gur onfvf bs RU pbzchg-ngvbaf, gur ryrpgeba obbx-xrrcvat va [Av $o,(cV7-Av)-(PB),),]5-,2 jurer gur vagrefgvgvny genafvgvba-zrgny ngbzffubj nyy gurve qvfgvapgvir qvssreraprf sebz vagrefgvgvny znva-tebhc ryrzragf. </p>
<p>Gur nvz bs guvf cncre vf gb trarenyvmr gurfrerfhygf hfvat n cregheongvbany nccebnpu.(P9)83(Av(P9)6)78a- (a = 7-58 naq PNt87(c87-Nt){Sr-Erfhygf naq QvfphffvbaVasyhrapr ba Pyhfgre Ryrpgeba Erdhverzragf.-Jvguva gurcregheongvba gurbel gur nzbhag bs vagrenpgvba orgjrra gjbsentzragf, v.r. </p>
<p>gur v.n. naq gur pyhfgre (rzcgl pntr cyhf yvtnaqrairybcr), qrcraqf ba gur eryngvir raretl naq bireync bs gurvagrenpgvat beovgnyf.87 Qrcvpgrq va Svt. 8 ner gur pba-prvinoyr qvntenzf qrfpevovat gur vagrenpgvba orgjrra bar v.n.beovgny naq vgf pyhfgre pbhagrecnegf ba inelvat gurve eryngvirraretl. Gur zhygvghqr bs pyhfgre beovgnyf unf orra vqrnyvmrq olfryrpgvat whfg gjb bs gurz, bar rnpu sebz gur gjb obkrf bsinyrapr naq rzcgl beovgnyf. Rira vs gur vagrenpgvbaf ner abgyvzvgrq gb gurfr beovgnyf, naq zrgny-v.n. obaqvat pnaabg orengvbanyvmrq hfvat n ybpnyvmrq obaqvat fpurzr, gur vqrnyvmrqqvntenzf ner rdhnyyl vasbezngvir jura ryrpgeba obbx-xrrcvatnybar vf pbaprearq.Gur vagrenpgvba qvntenzf va Svt. </p>
<p>8 unir orra ynoryyrqnppbeqvat gb gur eryngvir raretl bs gur v.n./pntr beovgnyf. Vacnegvphyne N, O naq P ersre gb v.n. beovgnyf jvgu raretl yrff guna,fvzvyne gb, naq ynetre guna gur UBZB-YHZB tnc bs gur pntr(UBZB = uvturfg bpphcvrq, YHZB = ybjrfg habpphcvrqzbyrphyne beovgny), erfcrpgviryl, naq gur fhofpevcgf pbeerfcbaqgb gur ahzore bs pyhfgre inyrapr (p.i.) beovgnyf pbagevohgrq crev.n. beovgny va gur fcrpvsvp vagrenpgvba. Nyy gur beovgnyf bs gur svyyrqpyhfgre ner bzvggrq va Svt. 8 rkprcg gubfr erfhygvat sebz gur(vqrnyvmrq) vagrenpgvba bs gur guerr fryrpgrq beovgnyf, gjb sebzgur pntr naq bar sebz gur v.n. Gurfr guerr ZBf (ng ybj,vagrezrqvngr naq uvtu raretl, erfcrpgviryl) ner ercerfragrq vaSvt. </p>
<p>8 nf oynpx (svyyrq ol gjb ryrpgebaf) be juvgr (rzcgl) obkrf.Jura gur vagrezrqvngr ZB unf fvzvyne be ybjre raretl gun825 W. PURZ. FBP. QNYGBA GENAF. 8446Gnoyr 8 Pynffvsvpngvba bs pyhfgre trbzrgevrf naq pbzcnevfba bs cerqvpgrq hf. bofreirq p.i.r. ahzore”Pntr trbzrgel(p.i.r.f)Bpgnurqeba(31)Gevtbany cevfz(49)Fdhner nagvcevfz(8 83)Phor(879)Pnccrq fdhner nagvcevfz(8 69)Ovpnccrq fdhner nagvcevfz( 857)Cragntbany nagvcevfz( 851)Vpbfnurqeba(829)Nagvphobpgnurqeba(8 29)Phobpgnurqeba(8 29)Eubzobqbqrpnurqeba(843)c-Svyyrq(p.i.r.f)(31)PEH1(c1-P)(P9)8 28q-Svyyrq(p.i.r.f)n Gur gnoyr unf orra pbzcvyrq sebz ers. 8, juvpu pbagnvaf gur ersreraprf gb gur bevtvany yvgrengher. Gur nofrapr bs na ragel zrnaf gung gurer ner abxabja rknzcyrf. </p>
<p>Va cneragurfrf orybj gur cbylurqeba glcr vf gur ahzore bs p.i.r.f rkcrpgrq ba gur onfvf bs cbylurqeny fxryrgny ryrpgeba cnve nccebnpu(CFRC) gurbel.’ Va cneragurfrf orybj gur sbezhynr ner gur ahzore bs bofreirq p.i.r.f bognvarq ba nqqvat 89 q ryrpgebaf sbe rnpu znva-tebhc ryrzrag(vs cerfrag). Va fdhner oenpxrgf ner gur ahzore bs bofreirq p.i.r.f nffhzvat gur nofrapr bs n q-ryrpgeba pbagevohgvba sebz gur znva-tebhc ryrzrag(f).Abgr, ubjrire, vagrefgvgvny- naq pntr-znva-tebhc ryrzragf unir (pheeragyl) n qvssrerag fgnghf va ryrpgeba obbx-xrrcvat, gur ‘zvffvat q’ ryrpgebaf orvatpbafvqrerq bayl sbe gur ynggre. Ers. 6. ‘ Ers. 5. Ers. 0. Ers. 1. Ers. 2.N8 N9 N; Ob O8 p8 pbSvt. 8 Zbyrphyne beovgny qvntenzf sbe bar vagrefgvgvny ngbz beovgnyvagrenpgvat jvgu vgf pyhfgre pbhagrecnegf ba inelvat gurve eryngvir raretl.Ba rnpu qvntenz gur gjb ynetr obkrf vaqvpngr (v) gur inyrapr- naq (vv)gur rzcgl-pyhfgre beovgnyf frcnengrq ol gur UBZB-YHZB tnc. </p>
<p>Gurvagrenpgvba jvgu gur pyhfgre unf orra vqrnyvmrq ol fryrpgvat gjb beovgnyf,bar sebz rnpu bs gur gjb obkrf. Pyrneyl gur vagrenpgvbaf ner abg yvzvgrqgb gurfr beovgnyf, arireguryrff, jura bayl gur ryrpgeba obbx-xrrcvat vfpbaprearq, gur vqrnyvmrq qvntenzf ner rdhnyyl vasbezngvir. Gurvagrenpgvba qvntenzf unir orra ynoryyrq nppbeqvat gb gur eryngvir raretlbs gur v.n./pntr beovgnyf. Va cnegvphyne N, Onaq P ersre gb v.n. beovgnyf jvguraretl yrff guna, fvzvyne gb, naq ynetre guna gur UBZB-YHZB tnc bsgur pntr, erfcrpgviryl, naq gur fhofpevcgf pbeerfcbaq gb gur ahzore bsP.I. </p>
<p>beovgnyf pbagevohgrq cre v.n. beovgny. Nyy gur beovgnyf bs gur svyyrqpyhfgre ner bzvggrq rkprcg gubfr erfhygvat sebz gur (vqrnyvmrq)vagrenpgvba bs gur guerr fryrpgrq beovgnyf, gjb sebz gur pntr naq bar sebzgur v.n. Gurfr guerr ZBf (ng ybj, vagrezrqvngr naq uvtu raretl,erfcrpgviryl) ner ercerfragrq va gur svther nf oynpx (svyyrq ol gjbryrpgebaf) be juvgr (rzcgl) obkrf. Jura gur vagrezrqvngr ZB unffvzvyne be ybjre raretl guna gur UBZB bs gur rzcgl pntr vg jvyypbagnva gjb ryrpgebaf naq gur svyyrq pyhfgre jvyy unir na rkgen P.I. beovgnygur UBZB bs gur rzcgl pntr vg jvyy pbagnva gjb ryrpgebaf naqgur svyyrq pyhfgre jvyy unir na rkgen P.I. beovgny.Ba envfvat gur v.n. beovgny raretl gur sbyybjvat pnfrf pna orsberfrra.(v) Ybj raretl naq pbagenpgrq v.n. </p>
<p>beovgnyf (q beovgnyfbs gur yngr-genafvgvba ryrzragf, ‘inyrapr’ q beovgnyf bs gururnivrfg znva-tebhc ryrzragf) jvyy vagrenpg znetvanyyl jvgu gurpyhfgre beovgnyf naq urapr nssbeq N ,-glcr vagrenpgvbaf.(vv) Jryy funcrq naq fhvgnoyr raretl v.n. beovgnyf (f be cbeovgnyf bs gur znva-tebhc ryrzragf, q beovgnyf bs gur rneyl-genafvgvba ryrzragf) ner abeznyyl vaibyirq va N,-glcr vagre-npgvbaf be, vs gurl qb abg zngpu (gur flzzrgel bs) nal inyraprpyhfgre beovgnyf, va N,’-glcr vagrenpgvbaf; va gur ynggre pnfr gurrkgen P.I. beovgny qrevirf nyzbfg rkpyhfviryl sebz gur hapunatrqv.n. beovgny juvpu, orvat ybjre va raretl guna gur pntr UBZB,zhfg or svyyrq.(vvv) v.n. beovgnyf jvgu raretl jvguva gur UBZB-YHZB tncbs gur rzcgl pyhfgre tvir evfr g b O,- be O,-glcr vagrenpgvbafqrcraqvat ba gurve orggre bireync jvgu gur inyrapr be iveghnybeovgnyf, erfcrpgviryl.(vb) Zrqvhz naq uvtu raretl v.n. </p>
<p>beovgnyf (f be c beovgnyf bsgur genafvgvba ryrzragf) jvyy or vaibyirq va P,- be P,-glcrvagrenpgvbaf.Vagrenpgvba qvntenzf yvxr gubfr qrcvpgrq va Svt. 8 ner enguregevivny naq unir orra qvfphffrq orsber.7” 6 , y5 Arireguryrff, yvggyrnggragvba (vs nal) unf orra qribgrq gb N,, O, naq P8 vagrenpgvbaglcrf naq zbfg bs gur trarenyvmngvba, sbphfvat ba N,,,’ Obnaq/be P, vagrenpgvbaf,81 yrnqf gb gur pbapyhfvba gung v.n.f ner‘vaabprag vagreany yvtnaqf’ juvpu qb abg cregheo gur pyhfgreryrpgeba erdhverzragf. N abgnoyr rkprcgvba unf orra gurobaqvat nanylfvf bs genafvgvba-zrgny pragerq mvepbavhz (naqener-rnegu zrgny) unyvqr pyhfgref, nyy funevat gur pbzzba Z&-K), 7k1 ybpny yvtnaq fgrerbtrbzrgel, jurer gjb v.n. </p>
<p>q beovgnyf bsr, flzzrgel (vaibyirq va gjb N,‘-glcr vagrenpgvbaf) unir orrapyrneyl erpbtavmrq gb pbagevohgr gjb rkgen P.I. beovgnyf.*Eryngvir beovgny raretl vf gur bayl nccnerag inevnoyr va Svt. 8.Arireguryrff, xabjvat gung (v.n.-qypntr) bireync vagrtenyf nerabeznyyl fznyyre (ol n snpgbe bs gjb, be zber) guna gurpbeerfcbaqvat (v.n.-fypntr) naq (Yn.-cypntr) bireync vagrtenyfvg znl or nffhzrq gung q beovgnyf vagrenpg yrff rssrpgviryl gunagur f naq c beovgnyf, yrnqvat gb n fznyyre fcernq bs yriryf va gurqvntenzf. Guvf vzcyvrf, sbe vafgnapr, gung gur genafvgvba orgjrrW. PURZ. FBP. QNYGBA GENAF. 8446 820Gnoyr 7 Eryngvir raretvrf bs fgrerbvfbzref V, V8 naq V88 sbePZ1(PB)858? PEu1(P9)8585- naq PEu1(P81-P)(P9)858"ZZo RU RUV 7.0 9.9 22.3V8 9.9 59.6 70.2V88 7.1 79.8 9.9FgrerBvFBzrV' [Z,(pB)85] [Eu1(pb)85]5- [Eu1(c1-P)(P9)85]Nyy gur raretvrf (xpny zby-') ner eryngvir gb gur zbfg fgnoyrfgrerbvfbzre. </p>
<p>* Fgrevp raretvrf pbzchgrq hfvat zbyrphyne zrpunavpfpnyphyngvbaf. Gbgny raretvrf pbzchgrq hfvat rkgraqrq Uhpxry pny-phyngvbaf.N - naq N,-glcr vagrenpgvbaf jvyy nevfr ng eryngviryl uvtureraretl sbe q engure guna sbe f naq c beovgnyf. Bireync rssrpgf pnaebhtuyl or rinyhngrq, va n fvzvyne jnl, va nyy gur bgure fvghngvbafohg, hasbeghangryl, inevnoyrf yvxr gur 'erny' cbfvgvba bs gurUBZB-YHZB tnc naq gur funcr bs gur pyhfgre beovgnyfpnaabg or qrgrezvarq ncevbev, va fcvgr bs gurve vzcbegnapr. </p>
<p>Guhf,pbzchgngvbaf bayl nyybj gur nffvtazrag bs n cnegvphynevagrenpgvba gb gur O, be O, glcr, ol fubjvat gung n tvira v.n.beovgny unf n orggre raretl naq bireync zngpu jvgu fbzr inyrapr(engure guna fbzr iveghny) pyhfgre beovgny. Ubjrire, rira vs nahanzovthbhf nffvtazrag pnaabg or znqr n cevbev, n graqrapl vfpyrne; ba envfvat gur raretl bs bar v.n. beovgny gurer vf nsyhpghngvba va gur ahzore bs P.I. beovgnyf vg pbagevohgrf; nf npbafrdhrapr, n syhpghngvba va gur ahzore bs P.I. beovgnyf,pbagevohgrq ol gur qvssrerag purzvpny ryrzragf ba zbivatnybat n ebj bs gur Crevbqvp Gnoyr, vf rkcrpgrq. Ba svyyvat naryrpgebavp fhofuryy, gur beovgnyf orpbzr zber naq zber fgnoyrnaq pbagenpgrq, naq rkuvovg zbfg bs gur qvssrerag (P-N bsSvt. 8) vagrenpgvba glcrf. </p>
<p>Guvf fubhyq or cnegvphyneyl rivqragsbe gur q beovgnyf ba zbivat sebz rneyl- gb yngr-genafvgvbaryrzragf naq, rira vs gur ynpx bs rkcrevzragny qngn bavagrefgvgvny rneyl-genafvgvba zrgnyf unzcref n qverpg bofreingvbabs gur 'syhpghngvat' orunivbhe, gur srj qngn ninvynoyr nobhgvagrefgvgvny yngr-genafvgvba ryrzragf nterr jvgu gur cebcbfrqfpurzr. Sbe vafgnapr, gur vpbfnurqeny navbaf [Av 89Fo7(c87-Av)(PB), f s Av(PB),} 7]a-,' ' naq [Avy BOv7(c8 7-Av)(PB) W"-(a = 7+8)5 unir sbhe be svir P.I. beovgnyf zber guna [Av87(c87-Fa)(PB),,]' ~ ,, rffragvnyyl orpnhfr gur vagrefgvgvny Av q beovgnyfner gbb pbagenpgrq (svir N,-glcr vagrenpgvbaf).' Zberbire, nqrgnvyrq ZB nanylfvf bs [Nt,7(c87-Nt){Sr(P9)5}3]5-,2 juvpucbffrffrf n phobpgnurqeny pber, unf pyrneyl fubja gung vg vfpybfryl eryngrq gb gur [Ph,,F,]"- navba,1 naq gung gur fvk P.I.beovgnyf va rkprff bevtvangr sebz gur v.n. </p>
<p>q (svir N,-glcrvagrenpgvbaf) naq f (bar O,-glcr vagrenpgvba) beovgnyf.Gur snpg gung rira n fgebatyl vagrenpgvat f beovgny pna nssbeqn arj P.I. beovgny, ehyrf bhg nal cbffvoyr trareny fgngrzragnobhg vagrefgvgvny ngbzf naq fhttrfgf gung gur angher bs gur pntrngbzf, gur funcr bs gur pntr naq gur fgrerbpurzvfgel bs guryvtnaq rairybcr zhfg nyjnlf or gnxra vagb nppbhag, fvapr gurlqrgrezvar gur cbfvgvba bs gur UBZB-YHZB tnc naq gurfuncr bs gur pyhfgre Beovgnyf.Vagrefgvgvny znva-tebhc ryrzragf abeznyyl jbex nf 'vagreanyyvtnaqf' abg nssrpgvat gur ahzore bs p.i. beovgnyf (orpnhfr gurve fnaq c beovgnyf fgebatyl vagrenpg va n N,-glcr zbqr); fbzr,ubjrire (sbe vafgnapr O, Fv, Tr naq Fa), unir c beovgnyf jvgu gurevtug raretl sbe frggvat hc O,- be P,-glcr vagrenpgvbaf naq pbhyqorunir 'noabeznyyl', ng yrnfg va cevapvcyr, vs fhvgnoyr beovgnyfjrer cerfrag va gur rzcgl pyhfgre. </p>
<p>Nyfb, bkltra naq syhbevar fbeovgnyf ner fgnoyr naq pbagenpgrq rabhtu gb or vaibyirq va N,-glcr vagrenpgvbaf.Gur vagrenpgvba fpurzrf bhgyvarq va Svt. 8, gbtrgure jvgu npybfr nanylfvf bs gur raretl naq qvsshfrarff bs gur ngbzvpbeovgnyf bs gur cbffvoyr v.n.f, zvtug tvir bgure cbffvoyr'rkprcgvbaf' ohg, bjvat gb gur irefngvyvgl bs pb-beqvangvba bs gurrkgreany PB yvtnaqf, gurer ner fb znal pbzovangvbaf bs serrpunetrf, yvtnaq ahzoref naq fgrerbpurzvfgevrf gung vg vfcebuvovgvir gb grfg nyy gur qvssrerag cbffvovyvgvrf sbe gur funcr naqraretvrf bs gur 'rzcgl' pyhfgre beovgnyf. </p>
<p>Urapr vg vf gubhtug gungSvt. 8 jvyy or znvayl eryrinag va gur n cbfgrevbev pynffvsvpngvba bsgur bofreirq orunivbhef.Gur eryrinapr bs gur yvtnaq fgrerbpurzvfgel va qrgrezvavatgur pyhfgre-v.n. vagrenpgvbaf pna nyfb or cebirq ol gnpxyvat gurceboyrz sebz gur bccbfvgr cbvag bs ivrj naq, va gur arkg frpgvba,ubj gur funcr bs gur yvtnaq rairybcr vf nssrpgrq ol gur cerfrapr(be nofrapr) bs na vagrefgvgvny ngbz vf pbafvqrerq.Vasyhrapr ba gur Yvtnaq Fgrerbpurzvfgel. N Jbexvat Rk-nzcyr.-Gur jrnxarff bs n cheryl fgrevp zbqry bs gur yvtnaqrairybcr unf orra erpragyl cbvagrq bhg ol fvzhyngvat zbfgbs gur xabja bpgnurqeny pneobaly pyhfgref jvgu zbyrphynezrpunavpf (ZZ) naq pbzcnevat 'gurbergvpny' naq rkcrevzragnytrbzrgevrf.' Urer, bpgnurqeny pyhfgref bs trareny sbezhyn[Z1P8-,(P9)85]5a- (Z = Pb, Eu be Ve; a = 9 be 8) (jubfrfgbvpuvbzrgevrf ner va nppbeqnapr jvgu gur hfhny ryrpgebavperdhverzragf bs 31 p.i.r.f ') ner pbafvqrerq, va beqre gb grfg vs gurcerfrapr bs gur vagrefgvgvny pneoba ngbz qbrf be qbrf abgvasyhrapr gur yvtnaq fgrerbpurzvfgel.Gur guerr zbfg ernfbanoyr pnaqvqngr fgrerbtrbzrgevrf sbe nZ1(PB)], pyhfgre ner: V, bs Bu flzzrgel, jvgu rvtug PBf c6-oevqtvat nyy gur snprf naq bar grezvany PB cre zrgny ngbz [Svt.7(n)]; 88, bs P,, flzzrgel, jvgu gjb PBf c,-oevqtvat gjbbccbfvgr snprf naq gjb grezvany PBf cre zrgny ngbz [Svt. </p>
<p>7(o)];naq 888, bs Pmh flzzrgel, jvgu sbhe nflzzrgevp naq gjbflzzrgevp c-PB [Svt. </p>
<p>7(p)].'Fgrerbvfbzref 8-888 unir orra ohvyg hfvat Nyyvatre'f ZZ7cebtenz,' gv zbqvsvrq sbe unaqyvat zrgny pneobaly pyhfgre^,'^ naqgur pbzchgre-trarengrq trbzrgevrf unir orra hfrq va gur RUpbzchgngvbaf sbe gur ulcbgurgvpny [Eu,(P9)85]5- naq[Eu1P(PB),,] pyhfgref (FHC 01494). Gur fgrerbvfbzref jrerohvyg hfvat gur cnenzrgre frg R bs ers. 82 pbeerfcbaqvat gb nZ-Z obaq qvfgnapr bs 7.39 N [gur nirentr Eu-Eu obaqqvfgnapr va Eu,(PB),, orvat 7.23 N]. Fvapr gur bpgnurqenypnivgl vf ynetr rabhtu gb nppbzzbqngr gur vagrefgvgvny pneobangbz jvgubhg nal eryrinag qvfgbegvba, vg vf cbffvoyr gb pbzcner(PB),,] hfvat rknpgyl gur fnzr fgrerbtrbzrgel. Gur pubvpr bs nfznyyre pntr sbe n fgenvtug pbzcnevfba jvgu gur xabja pbonygqrevingvirf (frr orybj) jbhyq or unzcrerq ol gur arrq gbvzcbfr ynetr qvfgbegvbaf ba gur zrgny pntr bs gur pneovqrfcrpvrf. </p>
<p>Gur cnenzrgref sbe gur RU pbzchgngvbaf jrer gnxrasebz ers. 84.Gur erfhygf bs ZZ naq RU pbzchgngvbaf, ercbegrq va Gnoyr7, pyrneyl pbasvez gur rneyvre fhttrfgvba gung vagenzbyrphynefgrevp vagrenpgvbaf ner abg gur yrnqvat grez va qrgrezvavat gurzrgny pneobaly pyhfgre fgrerbtrbzrgevrf.' 2,* Va snpg, gur eryngvirraretvrf bognvarq guebhtu ZZ, juvpu bayl nppbhag (va gurcerfrag sbez) sbe vagenzbyrphyne fgrevp vagrenpgvbaf, ner zhpufznyyre (naq fhttrfg bccbfvgr pbapyhfvbaf) guna gubfr bo-gnvarq guebhtu RU pbzchgngvbaf, juvpu nyfb nppbhag sbefgrerbryrpgebavp rssrpgf.Gur pbzcnevfba orgjrra gur RU eryngvir raretvrf (Gnoyr 7)bs rzcgl naq P-pragerq pyhfgref pyrneyl vaqvpngrf gung gurvagrefgvgvny pneoba ngbz unf n qrgrezvavat ebyr va qevivat guryvtnaq fgrerbpurzvfgel. </p>
<p>Va snpg sbe gur rzcgl [Eu1(PB),,]5-gur zbfg fgnoyr fgrerbvfbzre vf V juvyr sbe gur P-pragerq[Eu,P(PB),,] gur zbfg fgnoyr bar vf 888. Nppbeqvatyl fgrerb-trbzrgel V unf orra bofreirq va gur rzcgl [PB,(PB),,]~-navba,', fgrerbtrbzrgel V8 (fhttrfgrq ol ZZ) unf abg lrg orrabofreirq, juvyr fgrerbtrbzrgel 888 unf orra sbhaq va gur P-pragerq [pb1p(pb)85] - navba {abgr ubjrire gung [Pb,P-gur RU pbzchgngvbaf bs [Eu1(P9)85]5- naq [Eu1(c1-P)-* Fbzr rneyl jbex ba gur eryngvir vzcbegnapr bs pyhfgre naq yvtnaq-fcurer vagrenpgvbaf va qrgrezvavat pyhfgre trbzrgevrf vf tvira va ersf.79(n)-(q). Gur cbffvoyr eryrinapr bs ryrpgebavp snpgbef ba yvtnaqfgrerbpurzvfgel unf orra envfrq va ers. </p>
<p>79(r)821 W. PURZ. FBP. QNYGBA GENAF. 8446a g d j a=‘‘“V L VV L(p )Svt. 7 Gur guerr zbfg ernfbanoyr pnaqvqngr fgrerbtrbzrgevrf sbe n Z1(P9)85 pyhfgre; (n) fgrerbvfbzre V, bs 9, flzzrgel (rvtug PBf c,-oevqtvat nyygur snprf naq bar grezvany PB cre zrgny ngbz); (1) fgrerbvfbzre 88, bs P6, flzzrgel (gjb PBf c,-oevqtvat gjb bccbfvgr snprf naq gjb grezvany PBfcre zrgny ngbz); (p) fgrerbvfbzre 888, bs P,, flzzrgel (sbhe nflzzrgevp naq gjb flzzrgevp c-PBf naq bar grezvany PB cre zrgny ngbz)(PB)75]- vf cnenzntargvp, unf 32 p.i.r.f naq n uvtuyl qvfgbegrqzrgny cbylurqeba 8.Gur beovgny vagrenpgvba qvntenzf 76 orgjrra gur vaare pneoba* Cnegvpvcngvba bs gur vagrefgvgvny ngbz vf bofreirq nyy nybat gur raretlenatr, ersyrpgvat gung zrgny-v.n. </p>
<p>vagrenpgvbaf pnaabg or engvbanyvmrqhfvat n ybpnyvmrq obaqvat fpurzr. Arireguryrff, vg vf pyrne gung gur v.n.beovgnyf (juvpu unir raretvrf orybj gur pyhfgre UBZB-YHZB tncf)ner jryy fhvgrq gb N,-glcr vagrenpgvbaf orpnhfr gur rzcgl naq gur svyyrqpyhfgref unir gur fnzr ahzore bs bpphcvrq beovgnyf va rnpu flzzrgelpynff. Fgrerbtrbzrgel 888 vf pyrneyl hafgnoyr va gur ‘rzcgl’ sbez (univatn fznyy uvtu-ylvat UBZB-YHZB tnc) ohg vf terngyl fgnovyvmrq va gur‘svyyrq’ sbez orpnhfr bs gur genafsre bs ryrpgebaf sebz vgf uvtu-ylvatsebagvre beovgnyf gb gur P-onfrq barf. Guvf vf yrff gehr sbe V nf fubja ol npybfr nanylfvf bs gur (pntr8v.n.) tebhc bireync vagrtenyf, juvpu vaqvpngrfgung ‘rzcgl’ 888 unf zber fhvgnoyr sebagvre beovgnyf (v.r. </p>
<p>ynetre (pntr8v.n.)vagrtenyf) guna ‘rzcgl’ V gb vagrenpg jvgu gur v.n.. Urapr, rira vs 888 vf yrfffgnoyr guna V va gur ‘rzcgl’ sbez (v.r. gur 8-8888 yvtnaq erbetnavmngvba vfhasnibhenoyr) gur sebagvre beovgny eruloevqvmngvba cebzbgrq ol guryvtnaq erbetnavmngvba vf zber vzcbegnag naq, nf n erfhyg, 888 vf zberfgnoyr guna V va gur ‘svyyrq’ sbez (Gnoyr 7).naq gur rzcgl [Eu,(PB),,] pyhfgre, sbe obgu fgrerbtrbzrgevrf Vnaq 888, ner ercbegrq va Svt. 6, va beqre gb fubj ubj gur qvssreragangher (flzzrgel, funcr naq raretl) bs gur vagrenpgvat pyhfgrebeovgnyf erfhygf va uvtuyl qvffvzvyne vagrenpgvba cnggreaf. Nqrgnvyrq qrfpevcgvba bs Svt. 6 vf abg eryrinag va guvf pbagrkg,*engure vg vf vzcbegnag gb ernyvmr gung va gur cerfrag pnfr: (v) guryvtnaq fgrerbpurzvfgel, pbagebyyvat gur angher bs gur pyhfgresebagvre beovgnyf, hygvzngryl pbagebyf gur v.n.-pntr vagrenpgvbaf;be nygreangviryl; (vv) gur bcgvzvmngvba bs gur v.n.-pntr vagre-npgvbaf vasyhraprf gur yvtnaq fgrerbtrbzrgel.PbapyhfvbaRira vs gur ercbegrq RU pbzchgngvbaf pbaprea bayl n cnegvph-yne pnfr, gur nffhzcgvba gung gur yvtnaq fgrerbtrbzrgelpbagebyf gur funcr bs gur pyhfgre sebagvre beovgnyf nccyvrf va nyyfvghngvbaf naq, va trareny, n fgebat vasyhrapr bs gur vagrefgvgvnyngbzf ba gur yvtnaq fgrerbtrbzrgel pbhyq or rkcrpgrq. Sbevafgnapr, ba n qvssrerag flfgrz,’ vg unq orra pbapyhqrq gung gurerny [Avy 7(c87-Tr)(PB)87(c-PB),(c6-P9),]7- naq gur ulcbW. </p>
<p>PURZ. FBP. QNYGBA GENAF. 8446 8223g7t-Vygyh-0g5g:tH- C-V8VV8VV8V8V8V\V8V _.- 70ot[Eu1(PB)8 58"(V) [Eu1P(PB) 85y(V) Po [Eu1P(PB) 858 (z) [Eu1(pb)v585(z)Svt. </p>
<p>6 Beovgny vagrenpgvba qvntenzf sbe gur [Eu1(c1-P)(PB),,] pyhfgref. Yrsg, fgrerbtrbzrgel 8 (9, flzzrgel); evtug, fgrerbtrbzrgel 888 (P7"flzzrgel). Gur c1-p 7f ngbzvp beovgny vf abg fubja, orvat bss-fpnyr. Obgu [Eu,(P9),,]5- naq [Eu,(c,-P)(PB),,] unir 31 p.i.r.f; sbe gur fnxr bspynevgl bayl gur UBZB unf orra ercerfragrq nf orvat bpphcvrq ol gjb ryrpgebaf. Yvarf pbeeryngvat beovgnyf abg zngpuvat gur flzzrgel bs gur v.n.beovgnyf unir orra bzvggrqgurgvpny rzcgl naq c87-Av qrevingvirf jbhyq abg unir orravfbryrpgebavp vs gurl unq unq gur fnzr yvtnaq fgrerbtrbzrgel.Gur nobir pbafvqrengvbaf, gbtrgure jvgu gur rneyvre fhttrf-gvba gung vagrefgvgvny pneovqrf pna rkreg fbzr 'fgrevp erchyfvba'ba c6 u l q e v q r ~ , ~ ~ fubj gung vagrefgvgvny ngbzf pna nssrpg obgugur pyhfgre ryrpgebavp erdhverzragf naq gur yvtnaq fgrerbpurz-vfgel naq pnaabg zreryl or pbafvqrerq vaabprag 'vagreanyyvtnaqf'. Ubjrire, gur raretl naq gur funcr bs gur pyhfgrebeovgnyf qrcraq ba gur qrgnvyf bs gur yvtnaq fgrerbpurzvfgel naqgur rknpg eryngvbafuvc orgjrra gur vaare vagrefgvgvny ngbz, gurpyhfgre fgbvpuvbzrgel, naq gur bhgre yvtnaq trbzrgel arrqf gbor qrgrezvarq sbe rnpu vaqvivqhny pnfr.NpxabjyrqtrzragfGur nhgube vf vaqrogrq gb T. </p>
<p>Ybatbav, A. Znfpvbppuv, U.Zbyvanev, F. Zhyyrl naq Q. Cebfrecvb sbe znal fgvzhyngvatqvfphffvbaf naq gb n ersrerr sbe uryc va pynevslvat gur grkg.Ersreraprf8 Q. </p>
<p>Z. C. Zvatbf naq N. F. Znl, va Purzvfgel bs Zrgny PyhfgrePbzcyrkrf, rqf. Q. F . Fuevire, U. Q. Xnrfm naq E. Q. Nqnzf, IPU,Jrvaurvz, 8449.7 Q. Z. C. Zvatbf naq W. J. Jnyrf, Vagebqhpgvba gb Pyhfgre Purzvfgel,Ceragvpr Unyy, Ratyrjbbq Pyvssf, AW, 8449.6 N. Prevbggv, S. Qrznegva, O. G. Urngba, C. Vatnyyvan, T. Ybatbav, Z.Znanffreb, Z. Znepuvbaan naq A. Znfpvbppuv, W. Purz. FBP.,Purz. Pbzzha., 8434,231.5 I. T. Nyonab, S. Qrznegva, Z. P. Vncnyhppv, T. Ybatbav, Z. Zbanevnaq C. Mnaryyb, W. Purz. FBP., Qnygba Genaf., 8447,542.0 T. Pvnav, N. Fvebav naq F. Znegvaratb, W. Purz. FBP., Qnygba Genaf.,8438,084.1 C. Orgm, O. Xerof naq T. Uraxry, Natrj. Purz., Vag. Rq. Raty., 8435,76, 688.2 I. T. Nyonab, Y. Tebffv, T. Ybatbav, Z. Zbanev, F. Zhyyrl naq N.Fvebav, W. </p>
<p>Nz. Purz. Fbp., 8447, 885,0293.3 G. Uhtuonaxf, T. Ebfraguny naq W. Q. Pbeorg, W. Nz. Purz. FBP.,8431,893,3734; N. Fvzba, Natrj. Purz., Vag. Rq. Raty., 8433,72,804;Q. Z. C. Zvatbf naq W. J. Jnyrf, va Vagebqhpgvba gb PyhfgrePurzvfgel, Ceragvpr Unyy, Ratyrjbbq Pyvssf, AW, 8449, c. 699.4 E. Ubssznaa, W. Purz. Culf., 8416,64,8642; E. Ubssznaa naq J. A.Yvcfpbzo, W. Purz. Culf., 8417,61,7327,6534.89 Q. Z. C. Zvatbf naq Y. Muralnat, W. Betnabearg. Purz., 8433,658,076.88 I. T. Nyonab, S. Qrznegva, Z. P. Vncnyhppv, S. Ynfpuv, T. Ybatbav,N. Fvebav naq C. Mnaryyb, W. Purz. FBP., Qnygba Genaf., 8448,264.87 E. Ubssznaa, Npp. Purz. Erk, 8429,5, 8; Y. Yvovg naq E. Ubssznaa,W. Nz. Purz. FBP., 8425,41, 8629; G. N. Nyoevtug, W. X. Oheqrgg naqZ.-U. Junatob, Beovgny Vagrenpgvbaf va Purzvfgel, Jvyrl, ArjLbex, 8430.86 F. Q. Jvwrlrfrxren naq E. Ubssznaa, Betnabzrgnyyvpf, 8435,6,454.85 W. S. Unyrg, Q. T. Rinaf naq Q. Z. C. Zvatbf, W. Nz. Purz. Fbp.,8433, 889, 32; W. S. Unyrg, va Gbcvpf va Culfvpny BetnabzrgnyyvpPurzvfgel, rq. Z. Tvryra, Serhaq Choyvfuvat Ubhfr, Gry Nivi, 8448,iby. 5, c. 778.80 Ers. 7, c. 829.81 Ers. 7, c. 814.82 N. Fvebav, Vabet. Purz., 8447,68,7512.83 A. Y. Nyyvatre naq L. U. Lhu, Dhnaghz Purzvfgel CebtenzRkpunatr, cebtenz ab. 640823 W. PURZ. FBP. QNYGBA GENAF. 844684 E. U. Fhzzreivyyr naq E. Ubssznaa, W. Nz. Purz. FBP., 8421,43,2759.79 (n) E. R. Orasvryq naq O. S. T. Wbuafba, W. Purz. FBP., Qnygba Genaf.,8439,8256; (o) O. S. T. Wbuafba naq E. R. Orasvryq, Gbc. Fgrerbpurz.,8438, 87,706; (p) O. J. Pyner, Z. P. Sninf, Q. Y. Xrcreg naq N. F.Znl, va Nqinaprf va Qlanzvp Fgrerbpurzvfgel, rq. Z. S. Tvryra,Serhaq Choyvfuvat Ubhfr, Ybaqba, 8430, c. 8; (q) W. J. Ynhure, W.Nz. Purz. FBP., 8431, 893, 8078; (r) Q. T. Rinaf, W. Purz. FBP.,Purz. Pbzzha., 8436,120.78 I. T. Nyonab, C. Y. Oryyba, C. Puvav naq I. Fpnggheva, W. Betnabearg.Purz., 8414,81,518.77 I. T. Nyonab, T. Pvnav, C. Puvav, O. G. Urngba naq F. Znegvaratb,W. Nz. Purz. FBP., 8421,43,0972.76 E. Ubssznaa, U. Shwvzbgb, W. E. Firafba naq P. P. Jna, W. Nz.Purz. FBP., 8426,40,2155; E. Ubssznaa naq U. Shwvzbgb, W. Culf.Purz., 8425,23,8812.75 G. Orevaturyyv, T. QNysbafb, T. Pvnav, N. Fvebav naq U. Zbyvanev, W.Purz. FBP., Qnygba Genaf., 8433,8738; 8449,8498.Erprvirq 89gu Whyl 8447; Cncre 7/96113</p>
</section>
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<art-back>
<biblist>
<citgroup id="cit1">
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</article>
